Work /
Is 6500PLN/month enough for 2 people from India to live on in Wroclaw? [40]
Yes she is Flash/web developer
I she's good and has few years experience, then I don't see a reason why she would not find a company willing to apply for her job permit. In the end people in Poland are used to deal with bureaucracy. Being there of course will help, because face to face interview will be possible. If not that, then she can always work online through some freelance portal.
Another option to occupy time for you wife is to do master studies, for example in Politechnika Wrocławska is Computer Engineering master course in English: dwm.pwr.wroc.pl/other_programmes/597/master_programmes_in_english.html. It's one of top IT faculties in Poland (at least the one with Polish as lecture language) and graduates get work permit automatically, so she will have much easier to find a job.
I agree, i dont know, may be something part time to keep her busy, because new place+ no language + no work can be too much for her as she is work loving person
She will have no work permit to work part time. No company would apply for permit for part time employee.